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Updated: Jul 10, 2026

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents
09:45

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents

Published on: November 12, 2016

シラメタレーション経路からヒドリド ((トリアルキルシリル) シリルリチウムに至る

Takeaki Iwamoto1, Junichiro Okita, Chizuko Kabuto

  • 1Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan.

Journal of the American Chemical Society
|September 26, 2002
PubMed
まとめ

この研究は,二水素シランから陽子抽出を介してシリリチウムを合成するための簡単な方法を紹介しています. その結果生成された化合物は,ヒドリドシリリチウム1aのように,固体状態で安定した二次構造を示しており,X線結晶学で確認されています.

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