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Updated: Jul 6, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
11:45

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

ニトリルにアジドを加えることでテトラゾール形成のメカニズム

Fahmi Himo1, Zachary P Demko, Louis Noodleman

  • 1Department of Molecular Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

Journal of the American Chemical Society
|October 10, 2002
PubMed
まとめ

本研究では,アジドおよびニトリルからテトラゾール形成を調査しています. 密度関数理論の計算は,サイクル化に先立つ新しいニトリル活性化ステップを明らかにし,活性化バリアはニトリル置換物によって影響されています.

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Preparation of Nitriles01:12

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