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Updated: Jul 9, 2026

In Situ SIMS and IR Spectroscopy of Well-defined Surfaces Prepared by Soft Landing of Mass-selected Ions
10:22

In Situ SIMS and IR Spectroscopy of Well-defined Surfaces Prepared by Soft Landing of Mass-selected Ions

Published on: June 16, 2014

Ru(2) S(2) 複合体におけるヒドロキシル置換アルケーンおよびアルキンの脱水反応

Kazuko Matsumoto1, Yoshihiro Moriya, Hiroyasu Sugiyama

  • 1Department of Chemistry, School of Science and Engineering, and Advanced Research Institute of Science and Engineering, Waseda University and Japan Science and Technology Corporation, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555, Japan. kmatsu@waseda.jp

Journal of the American Chemical Society
|October 31, 2002
PubMed
まとめ

ルテニウム複合体は,ヒドロキシル置換アルケンおよびアルキンと反応し,脱水し,新しいC-S環構造を形成します. この研究では,様々な有機金属複合体を産生する分子間および分子内反応を調査しています.

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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction10:39

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Rate-Determining Steps03:08

Rate-Determining Steps

Relating Reaction Mechanisms
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Bronsted-Lowry Acids and Bases02:58

Bronsted-Lowry Acids and Bases

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Water: A Bronsted-Lowry Acid and Base

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Lewis Acids and Bases02:33

Lewis Acids and Bases

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Lewis Acids and Bases

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride01:26

Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride

Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
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