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Updated: Jun 25, 2026

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes
11:44

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes

Published on: November 12, 2016

デカメチラルミノセニウムカチオンにおけるアニゾトロプ的NMR相互作用テンザー

Robert W Schurko1, Ivan Hung, Charles L B Macdonald

  • 1Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada N9B 3P4. rschurko@uwindsor.ca

Journal of the American Chemical Society
|October 31, 2002
PubMed
まとめ

ビス (pentamethylcyclopentadienyl) アルミニウムカチオン, [Cp (pentamethylcyclopentadienyl) Al] (pentamethylcyclopentadienyl) [Cp (pentamethylcyclopentadienyl) Al] (pentamethylcyclopentadienyl) [Cp (pentamethylcyclopentadienyl) Al] (pentamethylcyclopentadienyl) [Cp (pentamethylcyclopentadienyl) Al] (pentamethylcyclopentadienyl) [Cp (pentamethylcyclopentadienyl) Al] (pentamethylcyclopentadienyl) +) は,フェロッセンのような,高い対称性を表している. NMRと計算方法により,その構造,ダイナミックなリング回転,およびアニゾトロプ的NMR相互作用が明らかにされ,そのユニークな性質が確認されました.

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