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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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タンタロセンの複合体に二水素を加えるメカニズムに関する研究

Dawn C Bregel1, Susan M Oldham, Richard Eisenberg

  • 1Department of Chemistry, University of Rochester, Rochester, New York 14627, USA.

Journal of the American Chemical Society
|November 15, 2002
PubMed
まとめ

この研究は,二水素がタンタルの中間物質に添加され,金属-炭素結合を直接渡らないことを明らかにしています. メタンの形成は,関連する複合体からのベンゼン形成よりも速い.

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