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Updated: Jul 16, 2026

Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
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ヴィニルフォスフィラン-フォスフォレンの再配置:ペリサイクル [1,3]-シグマトロピクシフトか否か?

Rosa E Bulo1, Andreas W Ehlers, Stefan Grimme

  • 1Department of Chemistry, FEW, Vrije Universiteit, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.

Journal of the American Chemical Society
|November 15, 2002
PubMed
まとめ

密度関数理論によると,2-ビニルフォスフィランは[1,3]-シグマトロピクシフトを経て,3-フォスフォレンを形成し,炭化水素類似体よりもエネルギーバリアが低い. Cr ((CO) ((5) との複合は,これらの再配列をさらに安定させる.

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