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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
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イソメリ化可能なアルケンの分子間結合は,ロジウム触媒によるC-H結合の活性化によるヘテロサイクルへの結合です

Kian L Tan1, Robert G Bergman, Jonathan A Ellman

  • 1Center for New Directions in Organic Synthesis, Department of Chemistry, University of California, Berkeley, CA 94720, USA.

Journal of the American Chemical Society
|November 21, 2002
PubMed
まとめ

この研究は,ロジウム ((I)) 触媒を用いた,非活性化アルケンのヘテロサイクルとの最初の分子間結合を導入する. 弱い酸はこれらの反応を著しく加速し,より広範な合成応用が可能であることが判明しました.

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