化学特異性クロム[VI]は,C−H結合の酸化を -40°C1で触媒化した

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Updated: Jul 17, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

Seongmin Lee1, P L Fuchs

  • 1Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA.

Journal of the American Chemical Society
|November 21, 2002
PubMed
まとめ

新しいクロムベースの酸化方法は,低温でC-H結合を効率的にアルコールまたはケトンに変換します. この強力な反応はステレオ化学的保持とともに進行し,オレフィンエポキシデーションを回避します.

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