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Updated: Jul 7, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

サイクロプロペネスにグリニャード反応剤を選択的に添加するための銅触媒法

Lian-An Liao1, Joseph M Fox

  • 1Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA.

Journal of the American Chemical Society
|November 28, 2002
PubMed
まとめ

銅で触媒化されたグリナード反応剤をサイクロプロペンに添加すると,キラル四次中心が形成されます. この方法は,優れたダイアステレオ選択性を持つ高度に機能化されたサイクロプロパンの合成を可能にします.

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