ベータ-ブチロラクトンとベータ-バレロラクトンのリング開きポリメリゼーションをポリ (((3-ヒドロキシアルカノアート) にするための単一サイトベータ-二酸化亜鉛触媒

関連する実験動画

Updated: Jul 15, 2026

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
08:46

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

Lee R Rieth1, David R Moore, Emil B Lobkovsky

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

Journal of the American Chemical Society
|December 19, 2002
PubMed
まとめ

この研究では,亜鉛アルコキシドイニシアターを使用して,ベータ-ブチロラクトン (BBL) とベータ-バレロラクトン (BVL) の迅速で軽度のポリメリゼーションが示され,制御された分子量を持つポリ・3-ヒドロキシブチラート (PHB) とポリ・3-ヒドロキシバレラート (PHV) が得られました. ポリメリゼーションは,提案されたモノメタリック活性種との調整挿入機構に従います.

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