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関連する概念動画

Constitutional Isomers of Alkanes02:18

Constitutional Isomers of Alkanes

Organic compounds of the same molecular formula can have different structural formulas called constitutional isomers, and the phenomenon is known as constitutional isomerism. Alkanes with four or more carbons showing multiple structures with the same molecular formula thereby exhibit constitutional isomerism.
The linear isomer of an alkane is prefixed by the term “n”; hence a linear isomer of pentane is known as n-pentane. Based on the type of branching, some of the branched isomers are given...
Nomenclature of Alkynes02:39

Nomenclature of Alkynes

Alkynes are unsaturated hydrocarbons characterized by the presence of carbon-carbon triple bonds and have a general formula CnH2n-2. The nomenclature of alkynes follows a set of rules similar to alkanes and alkenes; however, alkynes bear the suffix "-yne" instead of "-ane" or "-ene." There are two approaches to naming alkynes:
IUPAC Nomenclature of Aldehydes01:16

IUPAC Nomenclature of Aldehydes

Aldehydes are named based on the systematic nomenclature rules set by the IUPAC. For acyclic aldehydes, the longest carbon chain containing the aldehydic (–CHO) group is considered the parent chain. The aldehyde is named by replacing the last letter “e” in the hydrocarbon name with “al”. For instance, a simple, seven-carbon-membered acyclic aldehyde is called heptanal, derived from heptane. The carbon chain is numbered starting from the aldehydic carbon, although the aldehydic carbon’s locant...
Nomenclature of Carboxylic Acid Derivatives: Acid Halides, Esters, and Acid Anhydrides01:16

Nomenclature of Carboxylic Acid Derivatives: Acid Halides, Esters, and Acid Anhydrides

Naming Acid Halides
The IUPAC and common names of acid halides are derived from the corresponding carboxylic acids, by changing “ic acid” to “yl halide.” For example, as shown below, the IUPAC name ethanoyl chloride is derived from ethanoic acid, and the common name, acetyl chloride, is obtained from acetic acid.
Nomenclature of Aromatic Compounds with Multiple Substituents01:11

Nomenclature of Aromatic Compounds with Multiple Substituents

When more than one substituent is present on the benzene ring, the IUPAC nomenclature depends on the number of substituents present.
For disubstituted benzene derivatives, with two groups attached to the benzene ring, three constitutional isomers are possible. For example, consider dimethyl benzene, often called xylene, where the second methyl group can be substituted at the second, third, or fourth carbon. The relative position of the substituents is represented by prefixes ortho, meta, or...
Characteristics and Nomenclature of Copolymers01:24

Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...

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関連する実験動画

Updated: Jun 29, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

オクタクロロアズルレンとは,オクタクロロアズルレンである.

Yan Lou1, Joanne Chang, Jeffrey Jorgensen

  • 1Department of Chemistry, Dartmouth College, Hanover, New Hampshire 03755, USA. david.m.lemal@dartmouth.edu

Journal of the American Chemical Society
|December 19, 2002
PubMed
まとめ

研究者らは,ハロゲン化青素化合物であるペルハロアズレンを初めて合成した. この新しい合成は,ハロゲン化された芳香化合物とその独特の化学的性質を調査するための新しい道を開きます.

科学分野:

  • 有機化学 オーガニック・ケミストリー
  • ハロゲン化化合物 ハロゲン化化合物
  • アロマティック・システム

背景:

  • アズレンの誘導体は,独自の電子的および構造的特性で知られています.
  • パルハロゲン化アロマティック化合物は,しばしば明確な反応性と安定性を示す.
  • 新型ハロゲン化青素の合成は,依然として関心のある分野です.

研究 の 目的:

  • 最初のパルハロアズーレンを合成するために.
  • ヘキサクロアズーレンの塩素化行動を調査するために.
  • 塩素濃度が高いアズレール誘導体の反応性を調査する.

主な方法:

  • ヘキサクロロブタディエンとサイクロペンタディエンから1,3,4,5,6,7-ヘキサクロロアズーレンの合成.
  • ヘキサクロアズレンの電子性および自由基塩素化.
  • デカクロロテトラヒドロアズーレンの化学変換は,フォスファゼン塩基,酸触媒,および水銀による還元を用いて行われます.

主要な成果:

  • 最初のパーハロアズーレンの合成が成功しました.
  • ヘキサクロアズレンの塩素化は,添加によるもので,代用によるものではない.

さらに関連する動画

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
07:36

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

関連する実験動画

Last Updated: Jun 29, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
07:36

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

  • ラジカル塩素化によりデカクロロテトラヒドロアズーレンは得られます.
  • デカクロロテトラヒドロアズーレンは,反応条件に応じてノナクロロジヒドロアズーレン,ヘプタクロアズーレン,またはオクタクロアズーレンに変換できます.
  • オクタクロロアズーレンは繊細で,そのフッ素同位体に容易に変換することはできません.
  • 結論:

    • パーハロアズーレンの合成は達成可能である.
    • 高塩素化アズレンは,独特の加法および除去反応を示します.
    • オクタクロロアズーレンの安定性は,さらなるハロゲン交換反応を制限する.