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Updated: Jul 10, 2026

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
14:44

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR

Published on: December 16, 2013

J(Si-H) のNMR結合定数は,非古典的なH-Si相互作用の存在を本当に探しているのでしょうか?

Stuart R Dubberley1, Stanislav K Ignatov, Nicholas H Rees

  • 1Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, UK.

Journal of the American Chemical Society
|January 16, 2003
PubMed
まとめ

研究者はタンタール・ヒドロシリル複合体を合成し,異なる塩素置換でシリコン-ヒドリド結合定数の有意な増加を観察した. DFTの計算は,この傾向が債券強さと相関しないことを明らかにし, n=1.1.の場合で最も強い相互作用が起こります.

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2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)

Heteronuclear single-quantum correlation spectroscopy (HSQC) is a 2D NMR technique that reveals one-bond correlations between hydrogen and a heteronucleus. The HSQC experiment is similar to the heteronuclear correlation experiment (HETCOR) but is more sensitive. In the HSQC spectrum, the proton chemical shift is plotted on the horizontal F2 axis, while the 13C chemical shift is plotted on the vertical F1 axis. The corresponding proton and 13C spectra are also shown. The HSQC contour plot does...
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