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Updated: Jul 14, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

パイ・アリルニッケル (pi-allylnickel) (((N-ヘテロサイクリックカルベン) クロリド複合体との分子酸素の異常な反応性

Benjamin R Dible1, Matthew S Sigman

  • 1Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, UT 84112-8500, USA.

Journal of the American Chemical Society
|January 23, 2003
PubMed
まとめ

研究者は,単一のイミダゾル-2-イリデンのリガンドを持つ最初のニッケル (II) コンプレックスについて報告しています. これらの複合体は酸素と反応してジマーと不飽和カルボニル化合物を形成し,金属-酸素化学の洞察を明らかにします.

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