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Updated: Aug 6, 2026

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アミドとエステルのエノラートは静電学によって安定化されていますか?

Paul R Rablen1, Keith H Bentrup

  • 1Contribution from the Department of Chemistry, Swarthmore College, 500 College Avenue, Swarthmore, Pennsylvania 19081-1397, USA. prablen1@swarthmore.edu

Journal of the American Chemical Society
|February 20, 2003
PubMed
まとめ

静電安定化は,前述の仮定に反して,アミドとエステルのエノラート安定性にとって極めて重要です. 歪んだ構造は,共鳴ではなく,静電効果が酸性と塩基性を決定することを明らかにします.

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