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Updated: Jul 15, 2026

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
09:17

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

Published on: January 30, 2015

サイクロペンタディエニル置換剤は,グループ4のメタロセンの還元性除去反応に作用する:ダイナトロゲン活性化に対する運動学,メカニズム,応用

Jaime A Pool1, Emil Lobkovsky, Paul J Chirik

  • 1Contribution from the Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA.

Journal of the American Chemical Society
|February 20, 2003
PubMed
まとめ

ステリカルに要求される置換剤は,ジルコノコーセンの複合体における還元性除去を強化する. 巨大なシリル群を特徴とする新しい複合体は,ダイナトゲンの活性化を促進し,記録的な長さのN-N結合を持つ前例のないトリプルチルチルダイナトゲン複合体を形成します.

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