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Updated: Jul 5, 2026

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
07:28

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Published on: November 27, 2015

ヴィニル塩化物の反応は,遅い移行金属オレフィンポリメリゼーション触媒と反応する

Stephen R Foley1, Robert A Stockland, Han Shen

  • 1Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60037, USA.

Journal of the American Chemical Society
|April 3, 2003
PubMed
まとめ

ビニル塩化物 (VC) のポリメリゼーションは,金属複合体からのベータ塩素の急速な除去によって妨げられ,鎖の成長が妨げられます. このβ-Cl除去は,金属触媒によるVC挿入ポリメリゼーションの主要な障害である.

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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides07:50

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