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Updated: Jul 6, 2026

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Ir (I) システムによるハロアレンの選択的オルトC-h活性化

Eyal Ben-Ari1, Mark Gandelman, Haim Rozenberg

  • 1Departments of Organic Chemistry and Chemical Services, The Weizmann Institute of Science, Rehovot 76100, Israel.

Journal of the American Chemical Society
|April 17, 2003
PubMed
まとめ

カチオンのPNP-Ir (I) 複合体はベンゼンC-H結合を活性化し,安定したイリジウムフェニル水素を形成する. この複合体は,ハロベンゼンのオルトC-H結合を選択的に活性化させ,C-Hの誘導的活性化を示す.

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