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Updated: Aug 14, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Eステレオレギュラー1,1と1,3の構成単位は,高度に阻害されたc(2) の対称メタルロセーンによって触媒化されたコポリメリゼーションにおける1,3-ブタジエンの構成単位である

Pasquale Longo1, Stefania Pragliola, Giuseppe Milano

  • 1Università di Salerno, Dipartimento di Chimica Via S. Allende, I-84081 Baronissi Salerno, Italy.

Journal of the American Chemical Society
|April 17, 2003
PubMed
まとめ

高度に阻害されたメタルロセンの触媒は,エーテン/ブタジエンの共ポリメリゼーションにおける前例のないE-選択的1.1および1.3構成単位を可能にし,反応機構とステレオ選択性に関する洞察を明らかにします. これは,ポリマー化学の進歩を意味する.

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