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Updated: Jul 9, 2026

Synthesis of 1,2-Azaborines and the Preparation of Their Protein Complexes with T4 Lysozyme Mutants
08:56

Synthesis of 1,2-Azaborines and the Preparation of Their Protein Complexes with T4 Lysozyme Mutants

Published on: March 25, 2017

2-アザフェナレニル基の合成,特徴化,および調整化学

Shijun Zheng1, Jie Lan, Saeed I Khan

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA.

Journal of the American Chemical Society
|May 8, 2003
PubMed
まとめ

2-アザフェナレニル基が合成され,研究されました. フェナレニルラジカルとは異なり,容易に二酸化しないが,銅複合体で二酸化を誘導することができる.

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Nucleophilic Aromatic Substitution: Elimination–Addition01:11

Nucleophilic Aromatic Substitution: Elimination–Addition

Simple aryl halides do not react with nucleophiles. However, nucleophilic aromatic substitutions can be forced under certain conditions, such as high temperatures or strong bases. The mechanism of substitution under such conditions involves the highly unstable and reactive benzyne intermediate. Benzyne contains equivalent carbon centers at both ends of the triple bond, each of which is equally susceptible to nucleophilic attack. This 50–50 distribution of products is confirmed through isotopic...
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Preparation of 1° Amines: Azide Synthesis

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Aryldiazonium Salts to Azo Dyes: Diazo Coupling

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Amino Acid Biosynthetic Pathways

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