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Updated: Aug 11, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

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Published on: October 18, 2019

テトラメチルシランの触媒性アルコール溶解は,Pt媒介C-H結合の活性化による

Alan F Heyduk1, Jay A Labinger, John E Bercaw

  • 1Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125.

Journal of the American Chemical Society
|June 6, 2003
PubMed
まとめ

テトラメチルシランは,プラチナ触媒を用いて2,2,2-トリフッ素エタノールと反応し,シリルエーテルとメタンを形成する. この反応には,C-H結合の活性化と,シリコンに対する溶媒の攻撃が含まれます.

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