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Updated: Jul 16, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

ニトロソベンゼンを使用したアルファ-アミノオキシとアルファ-ヒドロキシケトンの触媒的エナンチオセレクティブ合成

Norie Momiyama1, Hisashi Yamamoto

  • 1Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, Illinois 60637, USA.

Journal of the American Chemical Society
|June 6, 2003
PubMed
まとめ

新しい触媒法により, (R) -BINAP-シルバー複合体を用いて,高度にエナチオセレクティブのニトロゾアルドール反応を可能にします. このアプローチは,高エナンチオ純度で貴重なアルファ-ヒドロキシケトンの前駆体であるアミノキシケトンを効率的に合成します.

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