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Updated: Jul 5, 2026

Determination of the Gas-phase Acidities of Oligopeptides
11:00

Determination of the Gas-phase Acidities of Oligopeptides

Published on: June 24, 2013

モノエステル,ダイエステル,トライエステルのリン酸移転反応とリン酸オ酸塩の比較:同位体効果の研究

Irina E Catrina1, Alvan C Hengge

  • 1Department of Chemistry and Biochemistry, Utah State University, Logan, UT 84322-0300, USA.

Journal of the American Chemical Society
|June 19, 2003
PubMed
まとめ

本研究では,バランスと動的同位体効果を用いて,リン酸チオ酸エステルとリン酸エステルを比較した. フォスフォロチオ酸エステルは,モノエステル反応ではより高度な離散グループ結合分裂を示しますが,ダイステルおよびトリエステル反応では少なくなります.

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