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Updated: Jul 18, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

非ヘム鉄 (II) 複合体による酸素活性化:アルファ-ケトカルボキシ酸対カルボキシ酸複合体

Mark P Mehn1, Kiyoshi Fujisawa, Eric L Hegg

  • 1Department of Chemistry and Center for Metals in Biocatalysis, 207 Pleasant Street Southeast, University of Minnesota, Minneapolis, MN 55455, USA.

Journal of the American Chemical Society
|June 26, 2003
PubMed
まとめ

アルファ-ケトカルボキシラートを含む鉄複合体は酸素を活性化し,非ヘム鉄酸化酸化酵素を模倣する. これらのモデルでは,水酸化と酸化性デカルボキシル化が行われ,酸素活性化におけるアルファ-ケト群の重要な役割が明らかになる.

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Anaerobic Protein Purification and Kinetic Analysis via Oxygen Electrode for Studying DesB Dioxygenase Activity and Inhibition

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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron07:56

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Oxidation of Alcohols02:37

Oxidation of Alcohols

In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, and their mechanism of action is provided.
The process of oxidation in a chemical reaction is observed in any of the three forms:
Oxidations of Aldehydes and Ketones to Carboxylic Acids01:15

Oxidations of Aldehydes and Ketones to Carboxylic Acids

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Loss of Carboxy Group as CO2: Decarboxylation of β-Ketoacids

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Reactivity of Enolate Ions

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Oxidation of Phenols to Quinones01:17

Oxidation of Phenols to Quinones

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Enolate Mechanism Conventions01:15

Enolate Mechanism Conventions

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C-attack...