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Updated: Jul 19, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

ペリレン・テトラパラジウムサンドイッチ複合体

Tetsuro Murahashi1, Tomohito Uemura, Hideo Kurosawa

  • 1Department of Applied Chemistry and Frontier Research Center, Faculty of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan. tetsu@chem.eng.osaka.u.ac.jp

Journal of the American Chemical Society
|July 10, 2003
PubMed
まとめ

研究者は,ビス-ペリレン-テトラパラジウムサンドイッチ複合体を合成し,ビス-アレン構造における最初の金属-金属結合鎖を特徴づけた. X線結晶学により,テトラパラジウム鎖が確認されました.

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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions19:58

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Metal-Ligand Bonds

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Stereoisomerism

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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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