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Updated: Jul 20, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

溶剤のない非対称なオレフィン・ヒドロフォーミレーションは,高度に交結したポリシュタイレンのサポートされた (R,S) -BINAPHOS-Rh(I) 複合体によって触媒化されます

Fumitoshi Shibahara1, Kyoko Nozaki, Tamejiro Hiyama

  • 1Conversion and Control by Advanced Chemistry, PRESTO, Japan Science and Technology, 1-8, Honcho 4-Chome, Kawaguchi 332-0012, Japan.

Journal of the American Chemical Society
|July 10, 2003
PubMed
まとめ

この研究では,ポリマーで支えられた触媒を用いた溶媒のない非対称な水酸化反応が実証されています. この方法は,様々なオレフィンを,高い選択性とエナチオ選択性を持つ有価なキラルアルデヒドに効率的に変換します.

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