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Updated: Jul 16, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
12:30

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

最初のトリプルチオール-チオラート水素結合と,二つの金属の中心を橋渡しするトリプルディセレニド結合です

Takumi Konno1, Kazuyuki Haneishi, Masakazu Hirotsu

  • 1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

Journal of the American Chemical Society
|August 2, 2003
PubMed
まとめ

ロジウム複合体を酸で2アミノエタネシオラートと2アミノエタネスレノラートで処理すると,明確なロジウム (III) 二重体が生じる. 硫黄複合体は水素結合によって二重体を形成し,セレニウム複合体は空気酸化によるデセレニド結合によって二重体を形成した.

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