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Updated: Jul 4, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

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パラジウムIIによる触媒C−H結合機能化:インドルの有酸素酸化無効化

Eric M Ferreira1, Brian M Stoltz

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|August 9, 2003
PubMed
まとめ

この研究では,酸素を用いてインドル環を形成するパラジウム触媒反応の詳細が示されています. ピリジンのリガンドの電子は,この効率的な酸化サイクル化プロセスで良い収量を達成するための鍵です.

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Preparation of Diols and Pinacol Rearrangement

Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
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