H2O2による鉄触媒オレフィンシスジヒドロキシル化:電愛性対核愛性メカニズム

Megumi Fujita1, Miquel Costas, Lawrence Que

  • 1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA.

まとめ

この研究では,オレフィン二酸化水酸化のための非ヘム鉄触媒を区別しています. クラスAの触媒は,電愛性行動を示し,クラスBの触媒は,異なる中間物質で核愛性反応を示します.

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