二核パラジウム複合体によって触媒化されたアルキンへの芳香C-H結合のステレオセレクティブシス添加

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Updated: Jul 17, 2026

Chemoselective Modification of Viral Surfaces via Bioorthogonal Click Chemistry
12:31

Chemoselective Modification of Viral Surfaces via Bioorthogonal Click Chemistry

Published on: August 19, 2012

Naofumi Tsukada1, Tomohiro Mitsuboshi, Hiroyuki Setoguchi

  • 1Department of Materials Chemistry, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan. tsukuda@aporg.che.tohoku.ac.jp

Journal of the American Chemical Society
|October 2, 2003
PubMed
まとめ

二核パラジウム複合体は,トライアルキルボランとアルキン水酸化を触媒化し,高度にステレオ選択的製品を生成します. 単位置換ベンゼン反応は,統計的にメタおよびパラ同位体を与え,オルト製品は見られなかった.

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Photochemical Electrocyclic Reactions: Stereochemistry

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Selection Rules: Photochemical Activation
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