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Updated: Jul 14, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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[Tp'W (((CO)) ((PhCCMe)) ((NH=CMeEt)) ][BAr (((4)) ]にダイアステロセレクティブヒドリドを加えたメチル/エチル分化

Neil J Vogeley1, Peter S White, Joseph L Templeton

  • 1Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, USA.

Journal of the American Chemical Society
|October 9, 2003
PubMed
まとめ

イミン複合体への水素添加は,同位体比に関係なく,高いダイアステレオ選択性を示しています. この選択性は,イミン複合体のEおよびZ同位体間の異なる運動酸性から生じる.

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