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Updated: Aug 18, 2026

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
11:17

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction

Published on: January 19, 2016

CO2とC2H4の金属補助C-C結合によるアクリラート形成:密度関数計算から明らかになった反応機構

Gábor Schubert1, Imre Pápai

  • 1Institute of Chemistry, Theoretical Chemistry Department, Chemical Research Center of HAS, Pusztaszeri út 59-67, H-1025 Budapest, Hungary.

Journal of the American Chemical Society
|December 4, 2003
PubMed
まとめ

この研究は,CO2−C2−H4結合機構を詳細に説明し,二核ヒドリド-アクリラート複合体を形成する熱外経路を明らかにしています. フォスフィンリガンドは,重要な反応段階において極めて重要であり,C−C結合形成を促進する.

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