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Updated: Jun 25, 2026

Determination of the Gas-phase Acidities of Oligopeptides
11:00

Determination of the Gas-phase Acidities of Oligopeptides

Published on: June 24, 2013

ベータ-デウテリウム同位体の効果は,アミンの基本性,"誘導性"およびステレオ化学的効果に起因する

Charles L Perrin1, Brian K Ohta, Joshua Kuperman

  • 1Department of Chemistry 0358, University of California, San Diego, La Jolla, California 92093-0358, USA.

Journal of the American Chemical Society
|December 5, 2003
PubMed
まとめ

デュテリウム同位体効果は,隣接するC−H結合のゼロポイントエネルギーを低下させることで,アンモニアイオンの基本性を高めます. この効果は,この効果です.

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