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動力的に不安定なステレオアイソマーの固体状態誘発制御

Joseph M Keane1, Fei Ding, Michal Sabat

  • 1Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901, USA.

Journal of the American Chemical Society
|January 22, 2004
PubMed
まとめ

プロキラルアレンを持つ金属複合体は,溶液中のダイナミックなダイアステロエーマーとして存在しますが,固体状態では単一のダイアステロエーマーとして存在します. この固体状態の選択性は,結合されたアレーンでのステレオ選択的反応を可能にします.

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