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関連する概念動画

Adhesion01:14

Adhesion

Adhesion occurs when one type of molecule is attracted to a different molecule. Water exhibits adhesive properties in the presence of polar surfaces, such as glass or cellulose in plants. For instance, when water is poured into a glass, the positively charged hydrogen molecules of water are more attracted to the negatively charged oxygen molecules in the silica than to the oxygen in neighboring water molecules.
Capillary action is a result of water’s adhesive tendencies. When a narrow glass...
Dehydration Synthesis01:15

Dehydration Synthesis

Dehydration synthesis (also called a condensation reaction) is the chemical process in which two molecules covalently link together to form a new molecule, along with the release of a water molecule. Many physiologically important compounds form by dehydration synthesis reactions, such as complex carbohydrates, proteins, DNA, and RNA.Synthesis of carbohydratesSugar molecules are covalently linked together by dehydration synthesis. During the reaction, the hydroxyl (-OH) group from one reactant...
Pinocytosis00:43

Pinocytosis

Cells use energy-requiring bulk transport mechanisms to transfer large particles, or large amounts of small particles, into or out of the cell. The cells envelop the particles in spherical membranes called vesicles or vacuoles. Vesicles that transport material into the cell are built from the cell membrane. These vesicles encapsulate external molecules and transport them into the cell in a process called endocytosis.
Xylem and Transpiration-driven Transport of Resources02:03

Xylem and Transpiration-driven Transport of Resources

The xylem of vascular plants distributes water and dissolved minerals that are taken up by the roots to the rest of the plant. The cells that transport xylem sap are dead upon maturity, and the movement of xylem sap is a passive process.
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Pinocytosis00:38

Pinocytosis

Cells use energy-requiring bulk transport mechanisms to transfer large particles or large numbers of small particles into or out of the cell. The cells envelop the particles in spherical membranes called vesicles or vacuoles. Vesicles that transport material into the cell are built from the cell membrane. These vesicles encapsulate external molecules and transport them into the cell in a process called endocytosis.
Pinocytosis ("cellular drinking") is one of three main types of endocytosis. In...

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関連する実験動画

Updated: Jul 8, 2026

In Situ Characterization of Hydrated Proteins in Water by SALVI and ToF-SIMS
09:48

In Situ Characterization of Hydrated Proteins in Water by SALVI and ToF-SIMS

Published on: February 15, 2016

陽子化されたダイペプチドに対する水分子の吸収.

Motoya Kohtani1, Gary A Breaux, Martin F Jarrold

  • 1Chemistry Department, Indiana University, 800 East Kirkwood Avenue, Bloomington, Indiana 47405, USA.

Journal of the American Chemical Society
|January 30, 2004
PubMed
まとめ

この研究では,陽子化されたダイペプチドに対する水分子の吸収を測定し,構造変化を含む複雑な相互作用を発見しました. 計算は実験上のエンタルピーとエントロピーの値と一致し,水がプロトネーション部位にどのように影響するかを明らかにします.

科学分野:

  • 物理化学 物理化学
  • コンピューティング・ケミストリー
  • バイオ物理化学 バイオ物理化学

背景:

  • 陽子化されたダイペプチドは,複雑な形状的行動を示す.
  • ペプチドと水の相互作用を理解することは,生物学的システムにとって極めて重要です.

研究 の 目的:

  • 陽子化されたダイペプチドに対する最初の水分子吸収の熱力学を測定し,計算する.
  • 水吸収時の形状の変化とプロトネーション部位の安定化を調査する.

主な方法:

  • 温度の関数としての均衡定数の実験的測定.
  • ペプチド-水複合体を分析するための密度関数理論 (DFT) とMP2計算方法.
  • 溶解されていないペプチドと水酸化ペプチドの適合分析.

主要な成果:

  • 水吸収のためのエンタルピー (DeltaH(o)) とエントロピー (DeltaS(o)) の実験的決定.
  • 計算により,ペプチドとその水複合体の2つの複数の低エネルギー構造が明らかになった.
  • 水吸収には,重要な形状の変化があり,N端のプロトネーション部位を安定させます.

結論:

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Proof-of-Concept for Gas-Entrapping Membranes Derived from Water-Loving SiO2/Si/SiO2 Wafers for Green Desalination

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Two-layered Membrane Sandwich Method for Laodelphax striatellus Saliva Collection
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関連する実験動画

Last Updated: Jul 8, 2026

In Situ Characterization of Hydrated Proteins in Water by SALVI and ToF-SIMS
09:48

In Situ Characterization of Hydrated Proteins in Water by SALVI and ToF-SIMS

Published on: February 15, 2016

Proof-of-Concept for Gas-Entrapping Membranes Derived from Water-Loving SiO2/Si/SiO2 Wafers for Green Desalination
09:39

Proof-of-Concept for Gas-Entrapping Membranes Derived from Water-Loving SiO2/Si/SiO2 Wafers for Green Desalination

Published on: March 1, 2020

Two-layered Membrane Sandwich Method for Laodelphax striatellus Saliva Collection
06:13

Two-layered Membrane Sandwich Method for Laodelphax striatellus Saliva Collection

Published on: August 27, 2021

  • 陽子化されたダイペプチドの水吸収は,ペプチド構造の影響を受ける複雑なプロセスです.
  • コンピューティング・メソッドは,実験的な熱力学データに対する貴重な洞察を提供します.
  • 二次アミンおよびカチオン-ピ相互作用のような特定の相互作用は,アドソルプションエンタルピーを調節します.