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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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ジルコニウム複合体による二酸化窒素からアンモニアへの水素化と割れ方

Jaime A Pool1, Emil Lobkovsky, Paul J Chirik

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University, Ithaca, New York 14853, USA.

Nature
|February 7, 2004
PubMed
まとめ

化学者は,穏やかな条件下で窒素と水素からアンモニア合成を達成します. 新しいジルコニウム複合体は,直接的なN-H結合形成を可能にし,窒素固定における1世紀の古い課題を克服しました.

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Catalysis

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The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
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Catalysis

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