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Updated: Jul 6, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

ルイス酸誘発のタンデム・ディエルス・アルダー反応/リング膨張は, [4 + 3] サイクル添加の同値である

Huw M L Davies1, Xing Dai

  • 1Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, USA. hdavies@acsu.buffalo.edu

Journal of the American Chemical Society
|March 5, 2004
PubMed
まとめ

塩化アルミニウムは,サイクロペンタディエンと不飽和アルデヒドの間のステレオ選択反応を触媒化する. このプロセスは,正式な [4 + 3] サイクル添加を経て,ダイエルス・アルダー反応と環膨張を経て製品を形成します.

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Introduction to Electrophilic Addition Reactions of Alkenes

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