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Updated: Jul 16, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
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遅い金属-炭素結合にイミン挿入して,安定したアミド複合体を形成する

Christopher Krug1, John F Hartwig

  • 1Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107, USA.

Journal of the American Chemical Society
|March 5, 2004
PubMed
まとめ

新しいアリルロジウム ((I) 複合体は,アリルイミンと反応し,安定したロジウムアミド挿入製品を形成する. 更に進行した反応は,β-水素の除去とサイクルメタレーションを含む複雑な経路を明らかにし,アミンとケチミンを生成した.

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