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Updated: Jul 1, 2026

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
08:46

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

ケトンとリチウムヘクサメチルジジラジラジドの反応:競争的なエノリゼーションと1,2-添加

Pinjing Zhao1, Anthony Condo, Ivan Keresztes

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

Journal of the American Chemical Society
|March 12, 2004
PubMed
まとめ

溶媒は,2-メチルサイクロヘクサノンがリチウムヘクサメチルジジラジル化物 (LiHMDS) とどのように反応するかに影響します. 溶媒によって,LiHMDSはエノライゼーションまたは1,2-添加反応を促進します.

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