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Updated: Jul 22, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Published on: April 10, 2018

Li+誘発のシグマ結合メタテシス:メチル交換のためのアリル,メチル交換は,メチル化されたモノカルバドデカボラートアニオン中のボロンで行われる

Zbynĕk Janousek1, Uwe Lehmann, Jakub Castulík

  • 1Department of Chemistry and Biochemistry, University of Colorado at Boulder, Colorado, USA.

Journal of the American Chemical Society
|April 1, 2004
PubMed
まとめ

190°Cのリチウムカルボラート誘導体とアリルシランとの間に新しいシグマ結合転移反応が観察されました. この反応にはアクティブなリチウムカチオンが必要で,アリラートカルボレートアニオンを生成し,その構造はX線結晶学で解明される.

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