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Updated: Jul 12, 2026

Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
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C-FとC-H結合の活性化をゼロヴァレンスのniとptによる比較:密度関数研究

Meike Reinhold1, John E McGrady, Robin N Perutz

  • 1Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

Journal of the American Chemical Society
|April 22, 2004
PubMed
まとめ

密度関数理論によると,ニッケル複合体はプラチナよりも選択的なC-F結合活性化に優れている. これは,C-H結合の活性化よりもC-Fに対する強い熱力学的好みと,より低い運動障壁によるものです.

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