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Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
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超臨界の二酸化炭素におけるディエルス・アルダー反応の溶媒恐怖加速度

Jin Qian1, Michael T Timko, Andrew J Allen

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|April 29, 2004
PubMed
まとめ

ディエルス・アルダー反応速度は,超臨界二酸化炭素 (scCO(2) で著しく増加し,アセトニトリルと比較して25倍加速を示した. このscCO(2) の反応性の向上は,ソルボホービックなメカニズムに起因する.

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