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Updated: Aug 17, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

パラジアム・フォスフィンで触媒化された分子間ヘック反応における地域化学の電子制御

Robert J Deeth1, Andrew Smith, John M Brown

  • 1Inorganic Computational Chemistry Group, Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK. r.j.deeth@warwick.ac.uk

Journal of the American Chemical Society
|June 4, 2004
PubMed
まとめ

密度関数理論は,パラジウム触媒のC−C結合における地域化学は,置換物の位置ではなく,電子構造によって支配されていることを明らかにする. 選択性指数は,さまざまな置換剤のビニレーションおよびアリレーション結果を正確に予測します.

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