移行金属・チオラート複合体の核好性の電子構造制御:実験的・理論的研究

Derek C Fox1, Adam T Fiedler, Heather L Halfen

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 West University Avenue, Madison, Wisconsin 53706, USA.

まとめ

新しい金属チオラート複合体は,ニッケルと亜鉛が鉄とコバルトよりも反応が速いことを示しています. この違いは電子構造によるもので,ニッケルが酵素における亜鉛の代わりになる可能性があるが,製品の放出は遅い可能性があることを示唆している.

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