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Updated: Aug 23, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

光学的に活性なアンサ-ジルコノセンのポリメリゼーション触媒を用いたキラルアルファ-オレフィンの運動解像度

Cliff R Baar1, Christopher J Levy, Endy Y-J Min

  • 1Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, CA 91125, USA.

Journal of the American Chemical Society
|July 1, 2004
PubMed
まとめ

新しいキラルジルコノセンの触媒は,大型オレフィンの効率的なポリメリゼーションを可能にし,ラセミックモノメアの運動解像度を達成します. この過程でエナチオマーが分離され,高同位性ポリマーと,反応が遅い同位体で濃縮された反応しないモノマーが得られます.

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