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Updated: Jul 18, 2026

A Strategy for Sensitive, Large Scale Quantitative Metabolomics
14:18

A Strategy for Sensitive, Large Scale Quantitative Metabolomics

Published on: May 27, 2014

アルファ,ベータ不飽和エステルの非対称的1,4-ヒドロシリレーション

Bruce H Lipshutz1, Jeff M Servesko, Benjamin R Taft

  • 1Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA. lipshutz@chem.ucsb.edu

Journal of the American Chemical Society
|July 9, 2004
PubMed
まとめ

JOSIPHOSまたはSEGPHOSのリガンドを持つ触媒性銅水化物 (CuH) は,エノア酸とラクトンの高度なエナチオセレクティブの1,4-減少を可能にします. この方法では,サブストラットとリガンドの比率は7700:1で,優れた効率性を示しています.

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