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Updated: Jul 12, 2026

Rapid Scan Electron Paramagnetic Resonance Opens New Avenues for Imaging Physiologically Important Parameters In Vivo
08:01

Rapid Scan Electron Paramagnetic Resonance Opens New Avenues for Imaging Physiologically Important Parameters In Vivo

Published on: September 26, 2016

サイトダイレクトの静電測定は,チオール特異のpH感受性窒酸化物で実施:高場EPRによる局所pKと極性効果の差異化

Alex I Smirnov1, Andres Ruuge, Vladimir A Reznikov

  • 1Department of Chemistry, North Carolina State University, 2620 Yarbrough Drive, Raleigh, North Carolina 27695-8204, USA. alex_smirnov@ncsu.edu

Journal of the American Chemical Society
|July 22, 2004
PubMed
まとめ

この研究では,電子パラ磁気共振 (EPR) を使用した正確なペプチドpKa決定のために,メタネチオスルフォン酸S-(1-オキシル-2,2,3,5,5-ペンタメチル-イミダゾリジン-4-イルメチル) エステル (IMTSL) を導入しています. IMTSLは,EPRスペクトルによるプロトネーション変化のモニタリングにより,サイト指向のpKa測定を可能にします.

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Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds11:44

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