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Updated: Jul 23, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

安定したアルキル複合体Ni (I) を製造し,その1電子酸化によりNi (II) 複合カチオンを形成する

Kristina D Kitiachvili1, Daniel J Mindiola, Gregory L Hillhouse

  • 1Searle Chemistry Laboratory, Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA.

Journal of the American Chemical Society
|August 26, 2004
PubMed
まとめ

新しいニッケル (I) アルキル複合体が合成され,ニッケル (II) カチオンに酸化されました. 予期せぬことに,これらのカチオンはガンマ-CH3デプロトン化を経て,予想されたイミドまたはフォスフィニデンの誘導体ではなく,メタラサイクロブタン製品を形成しました.

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