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Updated: Jul 8, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Rh2S2コアを持つ二核複合体上の分子水素の活性化:DFT計算とNMR機構学的研究

Andrea Ienco1, Maria José Calhorda, Joachim Reinhold

  • 1Istituto di Chimica dei Composti OrganoMetallici, CNR, Via Madonna del Piano, I-50019 Sesto Fiorentino, Firenze, Italy.

Journal of the American Chemical Society
|September 24, 2004
PubMed
まとめ

この研究では,二水素を活性化するロジウム-硫黄複合体を調査しています. DFT計算とNMR実験では,モノヒドリド-ム-ヒドロスルフィドの中間物質を明らかにし,二水素活性化の反応経路を明らかにした.

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