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Updated: Jul 5, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

挫折したベータ塩化物除去. アルファ-クロロノルボルネンによる選択的アレンアルキル化が,電性メタルロセニウムイオンペアによって触媒化された

Aswini K Dash1, Tryg R Jensen, Charlotte L Stern

  • 1Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA.

Journal of the American Chemical Society
|September 30, 2004
PubMed
まとめ

新しいシングルサイトポリメリゼーション触媒は,アルファ-クロロノルボルネンでアロマティック分子を効率的にアルキル化します. これらの触媒は,高回転周波数を持つエクソ-1-クロロ-2-アリルノルボルナン製品を,地域選択的に生成します.

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