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Updated: Jul 15, 2026

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
10:14

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography

Published on: May 16, 2014

高度に置換されたデルタ1-ピロリンをステレオ選択的に合成する:アズラクトンとエクソ選択的1,3-二極サイクロアディション反応

Satyamaheshwar Peddibhotla1, Jetze J Tepe

  • 1Department of Chemistry, Michigan State University, East Lansing, MI 48823, USA.

Journal of the American Chemical Society
|October 8, 2004
PubMed
まとめ

この研究は,アミノ酸由来ムンクノーンからピロリン基板を合成するためのシルバー触媒化された方法を導入しています. この反応は,アズラクトンとアルケンを用いて,不要な副作用なしにDelta1-ピロリンを効率的に生成します.

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Cycloaddition Reactions: Overview01:16

Cycloaddition Reactions: Overview

Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction

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Diels–Alder Reaction Forming Cyclic Products: Stereochemistry

The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.
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[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement

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Cyclohexenones via Michael Addition and Aldol Condensation: The Robinson Annulation

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Diels–Alder Reaction Forming Bridged Bicyclic Products: Stereochemistry

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